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Methyl ethyl ketone peroxideMEKP

An organic peroxide used as the initiator, commonly called the catalyst, for curing unsaturated polyester and vinyl ester resins at room temperature. It is corrosive and a strong oxidiser, requiring careful handling, storage away from accelerators, and accurate dosing to control gel time.

Also known as: MEK peroxide

Related terms

Catalyst

A substance that initiates or speeds a resin's curing reaction without being consumed in stoichiometric amounts. In the GRP trade the organic peroxide added to polyester resin, usually MEKP, is called the catalyst, although strictly it acts as an initiator.

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Accelerator

An additive that speeds the cure of a resin or adhesive, allowing curing at lower temperatures or in shorter times. Cobalt salts are the usual accelerators for polyester resins, working in combination with the peroxide catalyst; pre-accelerated resins have the accelerator already blended in by the manufacturer.

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Unsaturated polyester resin

UPR

A thermosetting resin dissolved in a reactive monomer, usually styrene, that cures by free-radical polymerisation when initiated with an organic peroxide such as MEKP. It is the workhorse matrix for glass-reinforced plastic in boat building, GRP roofing, tanks and vehicle panels, offering low cost and straightforward processing.

Resins & adhesivesComposites & laminatesRoofing & waterproofingAutomotiveConstructionMarineGreen energyIndustrial

Vinyl ester resin

VE

A thermosetting resin made by reacting an epoxy resin with an unsaturated acid and dissolving the product in styrene; it processes like a polyester but offers better toughness, chemical resistance and resistance to hydrolysis. Commonly specified for boat hulls, chemical plant, tank linings and as a barrier layer against osmosis.

Resins & adhesivesComposites & laminatesCoatings & protectionAutomotiveConstructionMarineGreen energyIndustrial

Gel time

The time taken for a mixed resin to change from a workable liquid to a soft gel that can no longer be applied or moved. It marks the practical end of the working period and is quoted by resin suppliers at a stated temperature and catalyst addition.

Resins & adhesivesAerospaceAutomotiveConstructionMarineGreen energyIndustrial

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